WSOLIDS1:
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This squeezed picture shows an example for the succesful simulation of a spectrum arising from the combined effect of chemical shift anisotropy and homonuclear dipolar coupling in a powder sample. It is the 31P NMR spectrum of tetraethyl diphosphine disulfide, shown as absorption and first derivative spectrum, and the results have been published in:
K. Eichele, G. Wu, R. E. Wasylishen, J. F. Britten:
Phosphorus-31 NMR Studies of Solid Tetraethyldiphosphine Disulfide.
A Reinvestigation of the 31P,31P Spin-Spin Coupling Tensor.
J. Phys. Chem. 1995, 99, 1030-1037.
Click on the picture to have a better look.
In addition to the chemical shift anisotropy (CSA), the spectrum of a spin pair will also depend on the direct dipolar coupling and potentially the indirect spin-spin coupling between both nuclei. Because both, the CSA and dipolar interaction, are tensorial interactions, the actual line shape also depends on their relative orientation.
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